Wood gas

Wood gas is a syngas, also known as producer gas, which is produced by thermal gasification of biomass or other carbon-containing materials such as coal in a gasifier or wood gas generator or producer gas. It is the result of two high-temperature reactions (above ): an exothermic reaction where carbon burns to CO2 but is then reduced partially back to CO (endothermic); and an endothermic reaction where carbon reacts with steam, producing carbon monoxide (CO), molecular hydrogen (H2), and carbon dioxide (CO2). In several gasifiers, the actual gasification process is preceded by pyrolysis, where the biomass or coal turns into char, releasing methane (CH4) and tar rich in polycyclic aromatic hydrocarbons (PAH). Other gasifiers are fed with previously pyrolysed char. Wood gas is flammable because of the carbon monoxide, hydrogen, and methane content.

Production

A wood gasifier takes wood chips, sawdust, charcoal, coal, rubber or similar materials as fuel and burns these incompletely in a fire box, producing solid ashes and soot (which have to be removed periodically from the gasifier) and wood gas. The wood gas can then be filtered for tars and soot/ash particles, cooled and directed to an engine or fuel cell to produce electricity. Most of these engines have severe purity requirements of the wood gas, so the gas often has to pass through extensive gas cleaning in order to remove or convert (i.e. to "crack" ) tars and particles. The removal of tar is often accomplished by using a water scrubber. Running wood gas in an unmodified gasoline-burning internal combustion engine may lead to problematic build-up of unburned compounds. The quality of the gas from different gasifiers varies a great deal. Staged gasifiers, where pyrolysis and gasification occur separately (instead of in the same reaction zone as was the case in e.g. the WWII gasifiers), can be engineered to produce essentially tar-free gas (less than 1 mg/m³), while single-reactor fluid-bed gasifiers may exceed 50,000 mg/m³ tar. The fluid bed reactors have the advantage of being much more compact (more capacity per volume and price). Depending on the intended use of the gas, tar can be beneficial as well by increasing the heating value of the gas. The heat of combustion of producer gas is rather low compared to other fuels. Taylor reports that "producer gas" has a lower heating value of 5.7 MJ/kg versus 55.9 MJ/kg for natural gas and 44.1 MJ/kg for gasoline. The heating value of wood is typically 15-18 MJ/kg. Presumably, these values can vary somewhat from sample to sample. The same source reports the following chemical composition by volume which most likely is also variable: alternative festival in New Zealand in 1981]]

Nitrogen N2: 50.9%
Carbon monoxide CO: 27.0%
Hydrogen H2: 14.0%
Carbon dioxide CO2: 4.5%
Methane CH4: 3.0%
Oxygen O2: 0.6%.

Usage in internal combustion engines

Wood gasifiers can power either spark ignition engines, where 100% of the normal petrol can be replaced with little change to the carburation, or in a diesel engine, feeding the gas into the air inlet that is modified to have a throttle valve, if it didn't have it already. On diesel engines the diesel fuel is still needed to ignite the gas mixture, so a mechanically regulated diesel engine's "stop" linkage and probably "throttle" linkage must be modified to always give the engine a little bit of injected fuel (Often under the standard idle per-injection volume). Wood can be used to power cars with ordinary internal combustion engines if a wood gasifier is attached. This was quite popular during World War II in several European and Asian countries because the war prevented easy and cost-effective access to oil. In more recent times, wood gas has been suggested as a clean and efficient method to heat and cook in developing countries, or even to produce electricity when combined with an internal combustion engine. Compared to WWII technology, gasifiers have become less dependent on constant attention due to the use of sophisticated electronic control systems, but it remains difficult to get clean gas from them. Purification of the gas and feeding it into natural gas pipelines is one variant to link it to the existing refueling infrastructure. Liquefaction by the Fischer-Tropsch process is another possibility.

Use in stoves, cooking and furnaces

Certain stove designs are in effect a gasifier working on the updraft principle - the air passes up through the fuel, which can be a column of rice husks, and is combusted, then reduced to carbon monoxide by the residual char on the surface. The resulting gas is then burnt by heated secondary air coming up a concentric tube. Such a device behaves very much like a gas stove. This arrangement is also known as a Chinese burner. An alternative stove based on the downdraft principle and typically built with nested cylinders also provides high efficiency. Combustion from the top creates a gasification zone with the gas escaping downwards through ports located at the base of the burner chamber. The gas mixes with additional incoming air to provide a secondary burn. Most of the CO produced by gasification is oxidized to CO2 in the secondary combustion cycle, therefore gasification stoves carry lower health risks than conventional cooking fires.

History

The first wood gasifier was apparently built by Bischof in 1839. The first vehicle powered by wood gas was built by Thomas Hugh Parker in 1901. Around 1900, many cities delivered wood gas (centrally produced, typically from coal) to residences. Natural gas began to be used only in 1930. Wood gasifiers are still manufactured in Singapore, China and Russia for automobiles and as power generators for industrial applications.

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Wood gas

Production

Usage in internal combustion engines

Use in stoves, cooking and furnaces

History

See also

References

External links