Proton

| mean_lifetime = > (stable) | electric_charge = +1 e | charge_radius = | electric_dipole_moment = | electric_polarizability = | magnetic_moment = | magnetic_polarizability = | spin = | isospin = | parity = +1 | condensed_symmetries = I( J P) = (+) | radius = ≤ }} The proton is a subatomic particle with an electric charge of +1 elementary charge. It is found in the nucleus of each atom, along with neutrons, but is also stable by itself and has a second identity as the hydrogen ion, H+. It is composed of three fundamental particles: two up quarks and one down quark.

Description

Protons are spin-½ fermions and are composed of three quarks, Protons and neutrons are both nucleons, which may be bound by the nuclear force into atomic nuclei. The nucleus of the most common isotope of the hydrogen atom is a lone proton. The nuclei of the heavy hydrogen isotopes deuterium and tritium contain one proton bound to one and two neutrons, respectively. All other types of atoms are composed of two or more protons and various numbers of neutrons. The number of protons in the nucleus determines the chemical properties of the atom and thus which chemical element is represented; it is the number of both neutrons and protons in a nuclide which determine the particular isotope of an element.

Stability

Protons are observed to be stable and their empirically observed half-life is at least . However, protons are known to transform into neutrons through the process of electron capture (also called inverse beta decay). "When a high energy-proton collides with an atom, it causes the ejection of an electron from the outer layer of the atom.":125 This process does not occur spontaneously but only when energy is supplied. The equation is: \mathrm{p}^+ + \mathrm{e}^- \rightarrow\mathrm{n} + {\nu}_\text{e} , where p is a proton, e is an electron, n is a neutron, and νe is an electron neutrino. The process is reversible; neutrons can convert back to protons through beta decay, a common form of radioactive decay. In fact, a free neutron decays this way with a mean lifetime of about 15 minutes.

Quarks and the mass of the proton

In quantum chromodynamics, the modern theory of the nuclear force, most of the mass of the proton and the neutron is explained by special relativity. The mass of the proton is about eighty times greater than the sum of the rest masses of the quarks that make it up, while the gluons have zero rest mass. The extra energy of the quarks and gluons in a region within a proton, as compared to the energy of the quarks and gluons in the QCD vacuum, accounts for over 98% of the mass. The internal dynamics of the proton are complicated, because they are determined by the quarks exchanging gluons, and interacting with various vacuum condensates. Lattice QCD provides a way of calculating the mass of the proton directly from the theory to any accuracy, in principle. The most recent calculations See this news report and links claim that the mass is determined to better than 4% accuracy, arguably accurate to 1% (see Figure S5 in Dürr et al.). These claims are still controversial, because the calculations cannot yet be done with quarks as light as they are in the real world. This means that the predictions are found by a process of extrapolation, which can introduce systematic errors. It is hard to tell whether these errors are controlled properly, because the quantities that are compared to experiment are the masses of the hadrons, which are known in advance. These recent calculations are performed by massive supercomputers, and, as noted by Boffi and Pasquini: “a detailed description of the nucleon structure is still missing because ... long-distance behavior requires a nonperturbative and/or numerical treatment..." More conceptual approaches to the structure of the proton are: the topological soliton approach originally due to Tony Skyrme and the more accurate AdS/QCD approach which extends it to include a string theory of gluons, various QCD inspired models like the bag model and the constituent quark model, which were popular in the 1980s, and the SVZ sum rules which allow for rough approximate mass calculations. These methods don't have the same accuracy as the more brute force lattice QCD methods, at least not yet.

The proton in chemistry

Atomic number

In chemistry the number of protons in the nucleus of an atom is known as the atomic number, which determines the chemical element to which the atom belongs. For example, the atomic number of chlorine is 17; this means that each chlorine atom has 17 protons and that all atoms with 17 protons are chlorine atoms. The chemical properties of each atom are determined by the number of (negatively charged) electrons, which for neutral atoms is equal to the number of (positive) protons so that the total charge is zero. For example, a neutral chlorine atom has 17 protons and 17 electrons, while a negative Cl− ion has 17 protons and 18 electrons for a total charge of −1. All atoms of a given element are not necessarily identical, however, as the number of neutrons may vary to form different isotopes, and energy level may differ forming different isomers. For example, there are two stable isotopes of chlorine: and .

Hydrogen as proton

Since the atomic number of hydrogen is 1, a positive hydrogen ion () has no electrons and corresponds to a bare nucleus with 1 proton (and 0 neutrons for the most abundant isotope ). In chemistry and biology therefore, the word "proton" is commonly used as a synonym for hydrogen ion () or hydrogen nucleus in several contexts:

The transfer of in an acid-base reaction is referred to "proton transfer". The acid is referred to as a proton donor and the base as a proton acceptor.
The hydronium ion (H3O+) in aqueous solution corresponds to a hydrated hydrogen ion. Often the water molecule is ignored and the ion written as simply (aq) or just , and referred to as a "proton". This is the usual meaning in biochemistry, as in the term proton pump which refers to a protein or enzyme which controls the movement of ions across cell membranes.
Proton NMR refers to the observation of hydrogen nuclei in (mostly organic) molecules by nuclear magnetic resonance. This method uses the spin of the proton, which has the value one-half.

History

The concept of a hydrogen-like particle as a constituent of other atoms was developed over a long period. As early as 1815, William Prout proposed that all atoms are composed of hydrogen atoms, based on a simplistic interpretation of early values of atomic weights (see Prout's hypothesis), which was disproved when more accurate values were measured. In 1886 Eugen Goldstein discovered canal rays (also known as anode rays) and showed that they were positively charged particles (ions) produced from gases. However, since particles from different gases had different values of charge-to-mass ratio (e/m), they could not be identified with a single particle, unlike the negative electrons discovered by J. J. Thomson. Following the discovery of the atomic nucleus by Ernest Rutherford in 1911, Antonius van den Broek proposed that the place of each element in the periodic table (its atomic number) is equal to its nuclear charge. This was confirmed experimentally by Henry Moseley in 1913 using X-ray spectra. In 1919 Rutherford proved that the hydrogen nucleus is present in other nuclei, a result usually described as the discovery of the proton.

Exposure

The Apollo Lunar Surface Experiments Packages (ALSEP) determined that more than 95% of the particles in the solar wind are electrons and protons, in approximately equal numbers. Because the Solar Wind Spectrometer made continuous measurements, it was possible to measure how the Earth's magnetic field affects arriving solar wind particles. For about two-thirds of each orbit, the Moon is outside of the Earth's magnetic field. At these times, a typical proton density was 10 to 20 per cubic centimeter, with most protons having velocities between 400 and 650 kilometers per second. For about five days of each month, the Moon is inside the Earth's geomagnetic tail, and typically no solar wind particles were detectable. For the remainder of each lunar orbit, the Moon is in a transitional region known as the magnetosheath, where the Earth's magnetic field affects the solar wind but does not completely exclude it. In this region, the particle flux is reduced, with typical proton velocities of 250 to 450 kilometers per second. During the lunar night, the spectrometer was shielded from the solar wind by the Moon and no solar wind particles were measured. Research has been performed on the dose-rate effects of protons, as typically found in space travel, on human health. The American Biostack and Soviet Biorack space travel experiments have also demonstrated the severity of damage induced by heavy ions on micro organisms including Artemia cysts.

Antiproton

CPT-symmetry puts strong constraints on the relative properties of particles and antiparticles and, therefore, is open to stringent tests. For example, the charges of the proton and antiproton must sum to exactly zero. This equality has been tested to one part in 10. The equality of their masses has also been tested to better than one part in 10. By holding antiprotons in a Penning trap, the equality of the charge to mass ratio of the proton and the antiproton has been tested to one part in .

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